To define a half reaction and relative mass action constant for each exchange species. In general, EXCHANGE_SPECIES is used in the file with the thermodynamic database, but additional information can be stored in the input file phreeqc.in. A specific block is available in the HYDRUS-1D GUI to provide additional thermodynamic data (Solute Transport – HP2 Definition: Additions to Thermodynamic Database).
EXCHANGE_SPECIES
association reactions
-add_constant
-add_logk
association reaction association reaction for an exchange species. The defined species is the first species at the right hand side of the equal sign.